Ask about this productRelated genes to: PDCL antibody
- Gene:
- PDCL NIH gene
- Name:
- phosducin like
- Previous symbol:
- -
- Synonyms:
- PhLP, DKFZp564M1863
- Chromosome:
- 9q33.2
- Locus Type:
- gene with protein product
- Date approved:
- 1996-07-26
- Date modifiied:
- 2016-10-05
Related products to: PDCL antibody
Related articles to: PDCL antibody
- Although palladium nanoparticles (PdNPs) are widely applied in catalytic, environmental, and biomedical contexts, the ecotoxicological and biosafety implications of biosynthesized PdNPs remain insufficiently characterized. In this study, PdNPs were synthesized using aqueous leaf extract of Dalbergia sissoo (DS-PdNPs). UV-Visible spectroscopy confirmed the reduction of PdCl to Pd, while FTIR analysis indicated biomolecules involved in the bio-reduction and stabilization of DS-PdNPs. TEM revealed an average particle size of 7.5 nm, and P-XRD confirmed the face-centered cubic (FCC) lattice structure. EDX indicated the elemental composition, and zeta potential measurements demonstrated good colloidal stability (-25 mV) of DS-PdNPs. The synthesized DS-PdNPs were evaluated for ecotoxicity and biosafety in Allium cepa (onion bulb) roots, Bacillus subtilis soil bacteria, and human keratinocyte (HaCaT) cells at concentrations of 1, 50, 100, 250, and 500 μg/mL. A dose-dependent response was observed, with A. cepa showing increased root growth inhibition after 3 days (84.37%), a decline in mitotic index (MI) of 66%, and elevated malondialdehyde (MDA) content (5.1 ± 0.14 nmol g FW). Conversely, HaCaT cells exhibited moderate cytotoxicity with an IC value of 261 μg/mL and 49.4% cell viability, while the bacterial assay showed a low toxicity profile characterized by a minimal zone of inhibition (7 ± 0.0 mm) at 500 μg/mL. These findings indicate the varied toxicity of DS-PdNPs across different test systems, highlighting their selective biological interactions and the need for careful evaluation of their overall environmental impact. - Source: PubMed
Publication date: 2026/05/14
Saifi IltishaAkhtar NazishSiddiqui M BGupta NancyVerma Sweety - Herein, we report the design and synthesis of m-bpy-MOF-PdCl, a heterogeneous single-site palladium catalyst constructed a mixed-linker metal-organic framework (MOF) strategy. In the carbonylation of iodobenzene, the catalyst exhibits exceptional activity under mild conditions without the need for a base. It also exhibits broad functional group tolerance, straightforward separation, and excellent recyclability over multiple cycles, with minimal loss of performance. - Source: PubMed
Publication date: 2026/05/13
Jiao YanFeng XinjiePan YuMa ZhongheYang HengGao PanChen Feng - A robust heterogeneous palladium catalyst was constructed by immobilizing a 1,10-phenanthroline-Pd(II) complex onto mesoporous SBA-15 silica via post-synthetic surface functionalization. The catalyst, SBA-15@PHEN-Pd(II), was prepared through sequential silylation of SBA-15, covalent anchoring of 5-amino-1,10-phenanthroline, and subsequent coordination with PdCl. Comprehensive characterization by TGA, XPS, atomic absorption spectroscopy (AAS), and Energy-dispersive X-ray spectroscopy (EDAX) confirmed successful surface modification and palladium immobilization. XPS analysis indicated that palladium is present in the + 2 oxidation state and coordinated to the phenanthroline nitrogens. SBA-15@PHEN-Pd(II) efficiently catalyzed CO-free carbonylation of aryl halides to carboxylic acids using a formic acid/DCC system. Systematic optimization identified DMF and NaOH at 120 °C as optimal, enabling up to 76% yield across a broad substrate scope. Reactivity followed the order Ar-I > Ar-Br > Ar-Cl, and substrates bearing electron-withdrawing substituents exhibited enhanced reactivity. Negligible palladium leaching was observed, and hot filtration experiments confirmed the heterogeneous nature of the catalyst. SBA-15@PHEN-Pd(II) exhibits sustained catalytic activity over six consecutive cycles, highlighting its stability and efficiency as a CO-free carbonylation catalyst. - Source: PubMed
Publication date: 2026/05/13
Fathinejad MaryamMansoori YagoubFekri SomayehAkinay YukselÇetin Tayfun - The reprocessing of spent nuclear fuel (SNF) and high-level waste (HLW) requires the development of selective methods for the extraction, separation, and monitoring of actinides, lanthanides, and toxic impurities. In this work, a series of alkyl-aryl diamides of 1,10-phenanthroline-2,9-dicarboxylic acid (DAPhen) were investigated as ionophores for potentiometric sensors and as ligands for various divalent metal ions and -elements. It was shown that the developed sensors exhibit pronounced potentiometric responses toward di- and trivalent cations. The sensitivity toward divalent metal ions increases when moving from alkaline-earth to transition and heavy metals and correlates well with the results of solvent extraction experiments. The sensors display reproducible responses toward trivalent lanthanide ions, with sensitivities decreasing along the lanthanide series, and some of the sensors also respond efficiently to Th and UO. For the first time, solid complexes of DAPhen ligands with Co(NO), Pb(NO), and PdCl were obtained and investigated by single-crystal X-ray diffraction. The Co complex exhibits an unusual seven-coordinate environment involving tetradentate ligand coordination and three water molecules in the inner coordination sphere. In the case of Pb, pronounced differences in the structures of complexes with chlorinated and nonchlorinated diamides were revealed, including the formation of dinuclear and mononuclear species with different coordination numbers. For Pd, square-planar complexes are formed, accompanied by a noticeable distortion of the phenanthroline core. Overall, the obtained results demonstrate the potential of DAPhen diamides for the development of potentiometric sensors and solvent extraction systems for the monitoring and reprocessing of spent nuclear fuel. - Source: PubMed
Publication date: 2026/05/13
Evsiunina Mariia VKazanina Darina AMatveev Petr IKalle PaulinaAvagyan Nane ALemport Pavel SKirsanov Dmitry OPetrov Vladimir GUstynuyuk Yuri ABabain Vasiliy ANenajdenko Valentine G - Although the two title palladium-N-heterocyclic carbene (Pd-NHC) complexes, namely, di-chlorido-{1-methyl-3-[2-(methyl-sulfan-yl)benz-yl]-2-imidazol-2-yl-idene-κ }(pyridine-κ)palladium(II) and di-bromido-{1-methyl-3-[2-(methyl-sulfan-yl)benz-yl]-2-imidazol-2-yl-idene-κ }(pyridine-κ)palladium(II), have the same formula type [Pd (CHN)(CHNS)] ( = Cl and Br), and the conformations of the corresponding mol-ecules are very similar, they crystallize in different space-group types: the PdCl complex in 1 with = 4 and two mol-ecules in the asymmetric unit, and the PdBr complex in 2/ with = 8 and one mol-ecule in the asymmetric unit. The symmetry relationship between the two crystal structures is of type with index 2 (t2). In both mol-ecular structures, the central palladium(II) atom has a slightly distorted square-planar coordination environment with the C- and N-bound organic ligands in a arrangement. In the crystals, weak C-H⋯ inter-actions lead to the formation of supra-molecular layers parallel to (010) for the PdCl complex and (100) for the PdBr complex. - Source: PubMed
Publication date: 2026/04/10
Weil MatthiasIelo LauraKathe Prasad MBica-Schröder Katharina