C_Kit Antibody (Y936)
- Known as:
- C_Kit Antibody (Y936)
- Catalog number:
- AE1008b
- Product Quantity:
- 0.1 mg
- Category:
- -
- Supplier:
- Abgen
- Gene target:
- C_Kit Antibody (Y936)
Related products to: C_Kit Antibody (Y936)
Related articles to: C_Kit Antibody (Y936)
- Delocalized [4n + 2]π-aromaticity in cyclic planar unsaturated organic molecules conceptually underpins organic chemistry. Recently, the study of all-metal aromaticity has burgeoned, but although there has been interest in cyclo-{E} (E = P, As, Sb, Bi) species as cyclopropenium analogues, the formation of cyclo-{Bi} remains rare. Thus, the potential aromaticity of 2/6π-cyclo-Bi, as the heaviest 6p analogue of cyclopropylium, has remained open to different interpretations. Here we report the formation of diuranium and dithorium 6π-cyclo-Bi inverse sandwich complexes, complementing the small number of acyclic- and cyclic-Bi (n = 3-5) compounds. The 6π-cyclo-Bi ring exhibits substantial ring currents, similar to 6π-benzene, 2π-(CH) or 6π-(CH). Calculations reveal similar ring currents for 6π-cyclo-Bi, 2π-cyclo-Bi and 0π-cyclo-Bi, demonstrating σ-aromaticity that is dominant over π-aromaticity in cyclo-Bi, despite the favourability of describing cyclo-Bi with localized rather than delocalized bond descriptions. Confirmation of 6π-cyclo-Bi σ-aromaticity provides the heaviest all-metal 6p analogue to π-aromatic (CH), leading to organic-inorganic aromaticity benchmarking. - Source: PubMed
Publication date: 2026/04/20
Ding JunruSeed John ABeuthert KatrinPeerless BenjaminRienmüller JuliaSchmidt AndreasWooles Ashley JNatrajan Louise SChen Chuan-LingSun Zhong-MingWeigend FlorianDehnen StefanieDu JingzhenLiddle Stephen T - Systemic inflammation impairs bone health by inhibiting the osteogenic differentiation of bone marrow stromal cells (BMSCs), thereby contributing to bone loss. Diallyl disulfide (DADS), a natural compound with anti-inflammatory properties, was investigated for its ability to mitigate inflammatory bone loss (IBL), reverse LPS-induced suppression of osteogenic differentiation, and elucidate the underlying mechanisms. - Source: PubMed
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